CIBA-GEIGY CORP -- FUNGINEX  -- 6840-00N064577
<pre>=====================  Product Identification  =====================

Product ID:FUNGINEX
MSDS Date:10/07/1993
FSC:6840
NIIN:00N064577
=== Responsible Party ===
Company Name:CIBA-GEIGY CORP
Box:18300
City:GREENSBORO
State:NC
ZIP:27419
Info Phone Num:800-888-8372
Emergency Phone Num:800-424-9300 (CHEMTREC)
CAGE:0267X
=== Contractor Identification ===
Company Name:CIBA-GEIGY CORP
Address:4917 DAWN AVE
Box:18300
City:EAST LANSING
State:MI
ZIP:48823-5605
Country:US
Phone:517-351-5900
CAGE:0267X
Company Name:CIBA-GEIGY CORP, AGRICULTURAL DIV.
Address:410 SWING ROAD
Box:18300
City:GREENSBORO
State:NC
ZIP:27419
Phone:800-888-8372 OR 800-334-9481
CAGE:8K340

=============  Composition/Information on Ingredients  =============

Ingred Name:CYCLOHEXANONE (CERCLA)
CAS:108-94-1
RTECS #:GW1050000
OSHA PEL:50 PPM, S
ACGIH TLV:25 PPM, S
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Ingred Name:EMULSIFIER BLEND; (EMULSIFIER)
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:TRIETHYLAMINE (CERCLA)
CAS:121-44-8
RTECS #:YE0175000
OSHA PEL:25 PPM
ACGIH TLV:1 PPM/5 STEL, S
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Ingred Name:PIPERAZINE, 1,4-BIS(1-FORMAMIDO-2,2,2-TRICHLOROETHYL)-;
    (TRIFORINE)
CAS:26644-46-2
RTECS #:TK9200000
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:SUP DAT: ON MD ADVICE. SKIN: WASH W/PLENTY OF SOAP & WATER,
    INCL HAIR & UNDER FINGERNAILS. DO NOT APPLY ANY (ING 6)
RTECS #:9999999ZZ

Ingred Name:ING 5: MEDICATING AGENTS EXCEPT ON MD ADVICE. REMOVE CONTAM
    CLTHG & WASH BEFORE REUSE. INHAL: MOVE VICTIM FROM (ING 7)
RTECS #:9999999ZZ

Ingred Name:ING 6: CONTAM AREA TO FRESH AIR. APPLY ARTF RESP IF NEC.
    NOTES TO MD: NO SPECIFIC ANTIDOTE IF INGESTED. SEVERAL (ING 8)
RTECS #:9999999ZZ

Ingred Name:ING 7: INGS OF THIS PROD ARE CORR/SEV IRRIT. CONSIDERATION
    SHOULD BE GIVEN TO GASTRIC LAVAGE OVER EMESIS FOR (ING 9)
RTECS #:9999999ZZ

Ingred Name:ING 8:STOM EMPTYING. CHECK FOR POSS MUCOSAL DMG BEFORE
    BEGINNING GASTRIC LAVAGE. FIVE G/KG OF ACTIVATED CHARCOAL(ING 10)
RTECS #:9999999ZZ

Ingred Name:ING 9: SUSPENSION (50G/400ML WATER) CAN BE GIVEN TO ABSORB
    REMAINING TOX. SPECIALIZED OPHTHALMOLOGIC ATTN IS (ING 11)
RTECS #:9999999ZZ

Ingred Name:ING 10: REC IN CASE OF EYE CONTAM. BASED ON ACUTE ORAL LD50
    IN RATS, INGEST OF APPROX 3 OZ MAY BE FATAL TO ADULT HUMAN.
RTECS #:9999999ZZ

Ingred Name:SPILL PROC: (PET LITTER). SWEEP UP MATL & PLACE IN APPROP
    CHEM CONTR. WASH SPILL AREA W/WATER CONTAINING STRONG (ING 13)
RTECS #:9999999ZZ

Ingred Name:ING 12: DETERGENT, ABSORB W/PET LITTER/OTHER ABSORB MATL,
    SWEEP UP & PLACE IN CHEM CONTR. SEAL CONTR & HANDLE (ING 14)
RTECS #:9999999ZZ

Ingred Name:ING 13: IN APPRVD MANNER. FLUSH SPILL AREA W/WATER TO
    REMOVE ANY RESIDUE. DO NOT ALLOW WASH WATER TO CONTAM WATER SUPP.
RTECS #:9999999ZZ

Ingred Name:EYE PROT: GOGGLES AND FULL LENGTH FACESHIELD .
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:LD50 (ORAL RAT): > 2000 MG/KG.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE: CAN CAUSE IRREVERSIBLE EYE
    INJURY & SUBSTANTIAL SKIN IRRIT. IF SWALLOWED, NAUS, VOMIT, BRTHG
    DFCLT, & CONVLS CAN OCCUR. INHAL MAY IRRIT NOSE & THROAT. INHAL OF
    HIGH CONCS OF ING 1 MAY CAUSE CNS  EFTS SUCH AS LABORED BRTHG,
    TREMORS & DECR HEART RATE. VERY HIGH EXPOS MAY CAUSE FATAL RESP
    DEPRESS. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: INGEST/ABSORPTION OF ING 1 THRU SKIN
    MAY CAUSE EFTS SIMILAR TO INHAL. PRLNG EXPOS TO LGE AMTS OF ING 1
    HAS CAUSED LIVER & KIDNEY DMG, & BLOOD & BONE MARROW EFTS IN
    EXPERIMENTAL ANIMALS. EXPO S TO ING 3 VAPS MAY CAUSE SEV EYE & RESP
    TRACT IRRIT/BURNS, CHEM PNEUMIT & PULM EDEMA. CHANGES IN LUNGS,
    LIVER,(SUP DAT)
Medical Cond Aggravated by Exposure:NONE KNOWN.

=======================  First Aid Measures  =======================

First Aid:IF POIS SUSPECTED, IMMED CONT MD, NEAREST HOSPITAL/NEAREST
    POIS CTL CTR. TELL PERS CONT COMPLETE PROD NAME, & TYPE & AMT OF
    EXPOS. DESCRIBE ANY SYMP & FOLLOW ADVICE GIVEN. INGEST: DO NOT
    INDUCE VOMIT.  IMMED GIVE LGE QTYS OF WATER TO DRINK & GET MED
    ATTN. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERS. APPLY ARTF RESP
    IF NEC. EYE: IMMED RINSE W/LGE AMT OF RUNNING WATER FOR AT LEAST 15
    MIN. (SUP DAT)

=====================  Fire Fighting Measures  =====================

Flash Point:122F,50C
Extinguishing Media:USE DRY CHEMICAL, FOAM, OR CARBON DIOXIDE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
    . EVACUATE NON-ESSENTIAL PERS FROM AREA TO PREVENT HUMAN EXPOSURE
    TO FIRE, SMOKE, FUMES/PRODS OF COMBUSTION.
Unusual Fire/Explosion Hazard:FUNGINEX IS AN NFPA CLASS IIIA
    COMBUSTIBLE LIQUID AND A DOT COMBUSTIBLE LIQUID. PREVENT USE OF
    CONTAMINATED BUILDINGS, AREA, AND EQUIPMENT UNTIL DECONTAMINATED.

==================  Accidental Release Measures  ==================

Spill Release Procedures:WEAR CHEM GOG W/SIDE SHIELDS/FSHLD, RUB
    GLOVES, RUB BOOTS, LONG-SLEEVED SHIRT, LONG PANTS, HAT & NIOSH/MSHA
    APPRVD CHEM CARTRIDGE RESP W/ORG VAP CARTRIDGE & PESTICIDE
    PREFILTER. FOR SML SPILLS, COVER  SPILL W/ABSORB MATL SUCH AS
    SWEEPING CMPD (ING 12)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:STORE MATL IN WELL-VENT, SECURE AREA,
    OUT OF REACH OF CHILDREN & DOMESTIC ANIMALS. DO NOT STORE FOOD,
    BEVERAGES/TOBACCO PRODS IN STORAGE AREA.
Other Precautions:PREVENT EATING, DRINKING, TOBACCO USAGE, AND COSMETIC
    APPLICATION IN AREAS WHERE THERE IS A POTENTIAL FOR EXPOSURE TO THE
    MATERIAL.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:TO AVOID BREATHING SPRAY OR MIST, WEAR
    NIOSH/MSHA APPROVED CHEMICAL CARTRIDGE RESPIRATOR WITH ORGANIC
    VAPOR CARTRIDGE AND PESTICIDE PREFILTER.
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Protective Gloves:NEOPRENE RUBBER GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS (ING 15)
Other Protective Equipment:RUB BOOTS, LONG-SLEEVED SHIRT, LONG PANTS, &
    HAT. EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA
    .
Work Hygienic Practices:ALWAYS WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
PH: 4.5-5.5 (10% SOLN). EFTS OF OVEREXP: KIDNEY, & HEART HAVE BEEN
    OBSERVED IN TEST ANIMALS EXPOS TO HIGH AMTS OF ING 3. PROD CONTAINS
    EMULSIFIER REPORTED BY ITS MFR TO BE EYE, SKIN, & RESP IRRIT. FIR
    ST AID PROC: HOLD EYELIDS APART TO RINSE ENTIRE SURF OF EYE & LIDS.
    DO NOT APPLY ANY MEDICATING AGENTS EXCEPT (ING 5)

==================  Physical/Chemical Properties  ==================

Spec Gravity:1.0756
pH:SUPDAT
Solubility in Water:MISCIBLE
Appearance and Odor:AMBER LIQUID, WITH AMMONIA-LIKE ODOR

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
ACIDS, ALKALIES, AND OXIDIZERS.
Stability Condition to Avoid:EXCESSIVE HEAT AND FIRE.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
    HYDROGEN CHLORIDE, DIMETHYLAMINE, AND OXIDES OF NITROGEN.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DO NOT REUSE PRODUCT CONTAINERS. DISPOSE OF
    PRODUCT CONTAINERS, WASTE CONTAINERS, AND RESIDUES ACCORDING TO
    LOCAL, STATE, AND FEDERAL HEALTH AND ENVIRONMENTAL REGULATIONS.

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.